the short answer
A typical pre-workout mixes caffeine, citrulline, beta-alanine, and sometimes creatine, plus flavoring. The honest truth is that most of what a client feels is the caffeine - at roughly 3 to 6 mg per kg it reliably lifts focus and output, and a strong coffee delivers nearly the same thing. The other ingredients have weaker or slower-acting evidence, and many blends underdose them.
This article is general information for coaches, not medical or dietetic advice - individual needs vary, so any client with a health condition, high blood pressure, stimulant sensitivity, on medication, or pregnant should check with a doctor or registered dietitian before using a stimulant supplement.